A Nuclear Primer -- It's All About Uranium
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Nuclear energy
is growing around the world after a twenty-five-year lull. Forty-four
reactors are under construction in China, Russia and India alone (NEI),
five in the United States, and over 600 are planned worldwide in the
next 30 years. Since there is a worry that nuclear energy can lead to
the proliferation of nuclear weapons, this might be a good time for a
nuclear primer.
The basic principles of nuclear physics and nuclear engineering are
the same for nuclear energy as for atomic weapons, and you must
understand them to produce either one. But that’s where the similarities
end.
Whether weapons or energy, it all starts with the element uranium
(U). Natural uranium is a fairly common material, occurring as a variety
of minerals in the ground, and consists of two isotopes. Isotopes of
any element have the same number of protons, but different numbers of
neutrons in the atom’s nucleus (see figure). Natural uranium is 99.3%
uranium-238 (U-238) and only 0.7% is uranium-235 (U-235).
U-235 is the fissile isotope, meaning it can be easily split
apart into smaller pieces. But 0.7% U-235 is not enough to sustain a
nuclear chain reaction in light water reactors and must be enriched
so there is more U-235. For commercial reactor fuel, U-235 is enriched
only to about 5% of the total U. The other 95% is still U-238. For
bombs, it needs to be enriched so that it is almost all U-235, over 93%.
Note – the Canadian CANDU reactor can use natural uranium but requires
heavy water.
U-235 consists of 92 protons and 143 neutrons, a combination that is
slightly unstable. If its nucleus is struck by a neutron at just the
right speed, it will split into two unequal parts, called fission
products, throwing off about three neutrons and some energy (see figure
above).
However, the real energy released is not radiation. It is the speed
at which the two fission pieces are moving away from each other. Since
they’re flying apart at near-light speed, there is an enormous amount of
kinetic energy released. The radiation is an after-thought (Dr. Judith Wright, The GeoPolitics of Energy).
This three-for-one split with respect to neutrons means that those
three neutrons can then split three other U-235 atoms releasing 9 more
neutrons, which can split 9 more U-235 atoms, releasing 27 more
neutrons, and so on. This is the nuclear chain reaction. If the
material is all U-235, as in weapons, then these neutrons see only more
U-235, and they all split in an uncontrolled chain reaction.
So within a microsecond, you have 10-to-the-26th, or
100,000,000,000,000,000,000,000,000 nuclei and neutrons flying apart,
some at near-light speed. The pressure and heat produced by this
uncontrolled chain reaction are extreme and causes a huge explosion plus
a momentary blast of neutrons. (More on bombs in the next post)
On the other hand, a commercial nuclear reactor is engineered to
contain and control this chain reaction. Nuclear fuel used in
commercial reactors is only enriched up to 5% U-235 of the total U, so
that most of the neutrons released hit the other natural isotope of
uranium, U-238 which does not split but captures the neutron and changes
into a new element (see figure above).
The reaction is easily controlled, it cannot explode like a bomb, and
the reactor just becomes a furnace that produces a lot of heat from the
released energy. That furnace turns water into steam, that turns a
turbine and produces electricity just like any coal or gas-fired
power plant.
The fragments produced when U-235 splits are new lighter elements,
the fission products. Most of the elements produced are non-radioactive
or not very radioactive, or have a short enough half-life that they
decay away in days or months, some in seconds.
While there some long-lived fission products like Tc-99 and I-129,
the two longest-lived elements that are really “hot” are strontium-90
(Sr-90) and cesium-137 (Cs-137) each with a half-life of about 30 years.
They only make up about 6% of the fission products, but they are what
make the waste hot. A rule of thumb is it takes seven half-lives for a
radioactive element to decay away to background. Because Sr-90 and
Cs-137 produce beta and gamma radiation, this makes the waste containing
them radioactive enough to require shielding for about 200 years.
After coming out of the reactor, spent fuel is placed in pools of
water for five years as all of the short-lived nuclides decay away so
just Cs and Sr are left, and the fuel cools off sufficiently to be put
in dry cement casks for 90 years or more as the Cs and Sr decays through
a few half-lives and gets much cooler.
Because of neutron capture, shown in the figure above, other elements
produced during the nuclear reactions include the heavy actinide
elements, the last row in the periodic table – plutonium, americium,
neptunium, and so on. When U-238 captures the neutron, it becomes U-239
which is also unstable (but not fissile), throwing off some beta
particles (the nucleus’ equivalent of an electron, essentially turning
neutrons into protons), and becomes plutonium-239 (Pu-239).
Similar parallel formation mechanisms exist for the other actinide
elements but Pu-239 is the main product of these reactions. Pu-239 is
also a fissile element, even more so than U-235, and can split to
produce additional energy. In fact, after only two years, so much Pu has
formed in the fuel that it’s producing as much energy as the original
U-235, but is being burned up just as fast.
After about five years, the fission products from both U and Pu build
up to the point where they scarf up so many neutrons that they poison
the reaction. The chain reaction then fizzles out, all neutrons stop,
and the fuel needs to be replaced. The fuel is not spent, only 5% of the
fuel is actually used. It just has too much junk in it. The fuel can be
recycled to make new fuel, or it can be set aside in dry-cask storage
for 90 years or more as the waste becomes much cooler. Eventually, it
can be burned in GenIV fast reactors
to produce over ten times the energy obtained from the first round of
burning, or it can be disposed of permanently in a deep geologic
repository.
Either way, cooler is easier and safer. This is why the NRC’s recent waste confidence
ruling is so important. It’s the Cs and Sr that makes nuclear waste
“hot”. The Pu, U and other actinides, while longer-lived, are not very
hot, not very radioactive, and produce almost no gamma radiation. The
actinides have long half-lives, thousands of years if they are not
burned up in new fuel, but being primarily alpha-emitters, they
are easily shielded and handled. Alpha radiation can be stopped by your
dead skin or 2 inches of air. Gamma and neutrons need three feet of
concrete or up to 300 feet of air to stop them.
Since it only takes about 5% ingrown fission products to poison the
reaction, the fuel can be recycled. If recycled, the fission products
are removed, the actinides and unused uranium are re-fabricated into new
fuel, and the small amount of waste is disposed of in a deep geologic
repository.
This whole process of commercial nuclear power is completely
different from atomic weapons. They are different enough processes to
easily choose one over the other. The primary difference between
commercial reactors and weapons reactors is what happens to the Pu
formed from the U-238 after neutron capture, and this topic will be the
subject of the subsequent Nuclear Primer – Bombs Versus Energy. Stay tuned!
Energy 3,579 views
Molten Salt Nuclear Reactors: Part Of America's Long-Term Energy Future?
The Electric Generation Fleet Is Changing
In the coming decades, an increasing number of coal and nuclear
baseload electricity plants will be retired. Coal is under growing
environmental pressure and a significant number of plant retirements are
in the pipeline. Meanwhile, the hoped-for nuclear renaissance has
fallen short of the initial anticipations, a casualty of concerns raised
by the catastrophe at Fukushima, as well as low natural gas prices that
have rendered uneconomic operation of even some current plants. (In the
United States a plant previously held in abeyance, Watts Bar, is about
to be licensed and four other plants are under construction. However,
the future pipeline is limited.) However, this leaves many to wonder
what will replace the power lost by these plant shutdowns. Wind and
solar resources can do their part, and are growing rapidly, but they are
intermittent sources of power and will require other resources (such as
gas-fired plants or storage) to complement them.
Gas plants are expected to fill much of the generating void. But even
with abundant shale gas reserves, supplies are not limitless and new
claims on the resource are rapidly emerging. These demands include
Liquid Natural Gas (LNG) conversion plants which ready gas for export to
overseas markets, gas-to-liquid facilities that convert methane to
diesel fuel, and an enormous potential growth in the petrochemical
industry eyeing domestic gas as a competitive feedstock.
As a consequence, a small number of analysts and companies are
suggesting that it is time to re-evaluate various molten salt reactor
technologies using thorium, spent nuclear fuel, or low enriched fuel.
And it is not only the U.S. that is looking at this technology. China
is forging ahead with plans to have both liquid and solid fuel
salt-cooled test reactors by 2017, while India is also evaluating the
technology (especially reactors powered by thorium – which it possesses
in abundance).
A Brief History Lesson
In 1946, a year after the U.S had dropped atomic bombs on Japan, it
was already evident that nuclear fission could be used not only for
bombs but for electricity production as well.
That year, Admiral Hyman Rickover began his program to power the U.S.
Navy’s vessels with nuclear reactors. A naval propulsion system based
on nuclear fission required the development of a relatively small
reactor, and the Navy ultimately settled on a pressurized water reactor
(PWR) that utilized solid fuel assemblies within a reactor vessel. The
pressure inside this vessel was equal to approximately 160 atmospheres,
allowing heated water – which otherwise would have turned to steam – to
remain in a liquid state at 330°C. This was useful in the production of
hot steam for electricity and propulsion. The Navy used the PWR
technology as its mainstay, installing PWRs in both nuclear submarines
and aircraft carriers.
In the early 1950’s, the U.S. began to focus on civilian energy
applications, which eventually led to the deployment of a 60 megawatt
nuclear plant (originally designed for aircraft carriers) being used to
power the domestic grid at Shippingport, Pennsylvania. The PWR reactor
technology was subsequently adopted for all future U.S. nuclear power
plants.
Later another version of this Light Water Reactor (LWR) technology,
called the Boiling Water Reactor (BWR) was also used in commercial
applications. Similar to the PWR, the BWR used essentially the same
solid fuel. However, the coolant actually boiled in the reactor and was
then sent directly to the turbine generators (without generating steam).
While BWRs had higher plant efficiencies, maintenance was more
complicated.
In the meantime, a competing nuclear technology was also being
developed by another branch of the U.S. Armed Forces. During the Cold
War against the Soviet Union, Air Force General Curtis LeMay wanted the
equivalent of a perpetually fueled nuclear submarine in the sky. His
goal was to develop a bomber fueled by a reactor that could keep the
plane endlessly circling the Soviet Union. Such a reactor would have to
be far lighter than that designed for submarines. It could not use the
thick container vessel and reactor shields associated with a PWR;
another technology would be needed. So in the early 1950’s Oak Ridge
National Laboratories (ORNL) was assigned to begin working on the
project.
The design ORNL came up with involved a small experimental 100
kilowatt reactor using molten uranium salts as its fuel. In 1954, the
first molten salt reactor (MSR) was built and operated successfully for a
brief period. High temperature salts were developed to deliver
high-temperature heat to the jet engines.
The Advantage of MSRs
The molten salt technology had several distinct advantages over the light water reactors:
Operating Pressure: The first inherent virtue was the fact
that MSRs operate at a much higher temperature without the need for high
pressure. While failure of the primary system at a PWR can result in a
highly pressurized release of radioactive material, MSRs operate at
atmospheric pressure. A failure would therefore not lead to dispersion
of radioactive materials such as was seen at Chernobyl.
Risk of Meltdown: Since an MSR is already operating in a liquid form with molten salts, by definition it cannot have a meltdown. A rupture of a pipe or the containment vessel would simply result in solidification of the molten salts with the radioactive elements remaining inert in a crystallized form.
Risk of Meltdown: Since an MSR is already operating in a liquid form with molten salts, by definition it cannot have a meltdown. A rupture of a pipe or the containment vessel would simply result in solidification of the molten salts with the radioactive elements remaining inert in a crystallized form.
Overall Stability: If the MSR creates too much heat, the
molten salts expand into the surrounding pipes. In such a case, the
chain reactions are reduced and the heat levels fall.
Passive Safety Systems: Oak Ridge created a simple back-up
safety system in the event of failure, in the form of a ‘freeze plug,’ a
salt plug kept cool by a fan. If the system loses power, the salt plug
melts and the liquid salt flows into a geometrically designed tank
where fission ceases to occur. This is significant, particularly when
compared to the systems utilized at today’s light water reactors such as
Fukushima. Although the Japanese facilities shut down immediately
after the initial earthquake, the resulting tsunami overwhelmed the
back-up electrical generators and battery systems necessary to keep the
system cool and stable. The reactors overheated, resulting in a
reaction that released hydrogen which accumulated in the containment.
This ultimately led to the explosions that ruptured the containment.
Lower Proliferation Risk:
Another advantage of the molten salt reactor is that it can run on
thorium, making it unsuitable for weapons use and therefore possessing
non-proliferation characteristics. Partly for that reason, in 2002 the
Generation IV International Forum (GIF – led by the European Atomic
Energy Community) anointed the MSR technology as one of six most
promising for future development.
While the bomber concept was eventually laid to rest, ORNL continued
to develop the technology for civilian purposes, and successfully ran a
7.4 megawatt (MW) molten salt reactor experiment (MSRE) from 1965 to
1969. However, in the early 1970s the federal government increased its
research and funding focus on other competing technologies and abandoned
the salt-based reactor technologies.
The Molten Salt Reactor Concept Resurrected
In the U.S., a small but growing community of advocates and investors
is actively pushing for an MSR renaissance utilizing thorium or other
fuel sources. These include – among others: the Energy From Thorium Foundation
(EFTF) of Cleveland, Ohio; Flibe Energy of Huntsville, Alabama; a U.S.
Department of Energy led consortium including the Massachusetts
Institute of Technology, the University of California, and the
University of Wisconsin; and Transatomic an MIT based start-up with $2
million in seed funding from the Founders Fund (led by Peter Thiel,
Founder of PayPal).
The EFTF’s Nuclear Operations and Project Management Consultant Dave Amerine is a converted former nuclear engineer with 45 years in the nuclear industry, a storied career,
and experience on the leadership teams of eight different nuclear
plants. He’s a passionate believer in salt-based nuclear technologies
and convinced that a thorium-based MSR would ultimately be safer and
cheaper than the current pressured light water technologies in use
today. Amerine comments that, in particular, the nuclear waste issue is a
huge comparative advantage worthy of consideration:
Unlike light water reactors where we only consume about 5% of available fuel and then we remove the rods for structural integrity considerations, with fuel in a hot and highly radioactive state, in the LFTR (liquid fluoride thorium reactor), almost 100% of the fuel is consumed.
The resultant waste when you shut down a molten salt reactor is a lot less in volume and over 80% is short lived, with most decaying to acceptable levels in approximately ten years…A small amount would take 300 years to reach safe radioactive levels, but that is more manageable compared with 10,000 years with waste from a light water reactor.
There is still little practical experience with MSR technologies, but
Amerine believes that the lifespan of an MSR could be considerable.
They are building naval light water reactors to last 60 years…they (MSRs) could probably last even longer, perhaps 80 years or more.
He believes decommissioning would probably cost a lot less than a
traditional light water reactor as well. He also mentioned that fuel
enrichment and fabrication costs could also be avoided and containments
would not have to be as robust, resulting in costs being as much as 50%
less than today’s LWRs.
Meanwhile, other countries are forging ahead and Amerine is concerned
that the U.S. may lose its original leadership role in this technology
in particular and nuclear power in general, because there is little
government support to explore the possibilities.
China, India, the Czech Republic and Russia are exploring this technology. We are virtually stalled because we don’t have a national resolve to address a pending problem, which is our energy crisis… If you read Dr. Moniz’s (the current Secretary of Energy) strategic plan for the DOE, it does not mention nuclear. Instead it is in pursuit of solar, wind, and biomass. None of these technologies would be sustainable without significant government subsidies.
The Challenge of Promoting and Developing a New Technology
Amerine opines that the slow pace relative to the MSR technology in
the U.S. is partially a result of the regulatory and government mindset.
Those who do have an understanding of nuclear-related technologies have
generally become “light water reactor centric,” which he fears will
keep the U.S. from seriously evaluating the molten salt reactor path.
If you look at the generation 4 reactors which are the future reactors on the DOE nuclear power list, the MSR is at the bottom of the list.
Amerine acknowledges that it is a heavy lift – potentially involving
several decades of research, money, and regulatory processes – to get
from MSR concept to commerciality. The first thing one would need is a
small research reactor to (re)prove the concept and address unresolved
technology issues from the 1960s. That would likely then lead to a test
reactor and finally to a demonstration reactor. The problem is that
this would fall under DOE auspices and require congressional support –
at a time when the dysfunctional congress cannot agree on anything, let
alone a potentially promising energy technology that requires long lead
times and potentially billions of dollars.
Amerine’s colleague at EFTF, lawyer Michael Goldstein, who has
experience as an electric utility attorney at a nuclear power plant and
Navy nuclear submarine duty, comments that licensing is a very big issue
and that the existing regulatory structure is not established to
address the thorium or other molten salt technologies. There are no
current regulations applicable specifically to molten salt reactors, and
these rules will have to be created before licensing. He notes that
there is investor interest, but money will likely stay frozen until
regulatory issues get ironed out.
Nobody’s willing to wait 20 years to find out if they could get a return on their investment…People and technologies are ready if there were a path to licensing.
Transatomic Power: A Promising Company Making Steps Forward
Even as most of the investment community waits on the sidelines,
there are a few initiatives that continue to advance. One of the most
interesting is the work of Transatomic Power.
Co-founded by two MIT Ph.D. students, the company is focused on
developing a molten salt reactor fueled with nuclear waste. Conventional
light water reactors consume less then 5% of the potential fission
energy in uranium. The Transatomic Power reactor design is focused on
harvesting the 95% or more energy in the fuel that remains. CEO Leslie
Dewan and CTO Mark Massie examined existing nuclear technologies and
quickly became convinced that the molten salt reactor was the best
technology for today’s world.
The ability to achieve high burn-up rates at atmospheric pressure was desirable. We also liked that one had been tested at Oak Ridge National Labs which ran for 20,000 hours. That showed this type of plant was viable.
The team felt that the ORNL design needed some significant re-design:
It was bulky, expensive, had a low power density, and required highly
enriched fuel. The design was highly accident-resistant, but its high
cost and low power density prevented its broader adoption, Dewan notes,
“in part because there had been no nuclear accidents at that point, and
nobody wanted to make the trade-off (between cost and safety).”
Transatomic Power opted to change the ORNL design in some fundamental ways. The first thing they did was to determine how to make the plant run on nuclear waste. The company then changed the moderator. The ORNL design used graphite as a moderator (a moderator slows neutrons down to the correct energy level, to make them more likely to induce fission), but it required approximately 90% of its core to be graphite. For its moderator, Transatomic uses zirconium hydride, clad with a silicon carbide based composite. Zirconium hydride is much more effective at slowing down neutrons, so only 50% of its core has to be moderator.
The company also changed the salt. The ORNL design used a lithium
fluoride – beryllium fluoride salt, but this salt can only contain a
very small amount of dissolved uranium. Transatomic instead uses a
lithium fluoride – uranium fluoride salt, which can contain about 27
times more uranium. Together, these two changes to the moderator and
salt allow the reactor to run on either very low-enriched fresh uranium
fuel or spent nuclear fuel.
Dewan is looking to the future when coal plants are retired en masse,
and she has designed the new units to be suitable as similarly sized
replacements, at 520 megawatts of electric generating capacity. But much
stands between today’s blueprints and future commerciality, and the
company is focused on key experimental tests.
The main thing we are starting to do is to start tests concerning corrosion effects and component lifetimes in the reactor itself.
Transatomic’s CEO is reluctant to offer a timeline for
commercialization, noting that the outcome will be heavily driven by the
regulatory process.
It’s one of the biggest hurdles. On the technology side, we will have all of the technical and design work done within the next two or three years. Then we will need to build a demo site at a national laboratory to get data for the Nuclear Regulatory Commission (NRC).
Dewan estimates that the demonstration site would likely cost three
hundred million dollars for licensing, construction, and operation. To
date, the company has had only informal discussions with the NRC. It has
been in conversations with a joint DOE and NRC initiative for
developing a licensing pathway for advanced reactor technology, and the
DOE has been working on this for over a year.
Finally, Dewan observes that Transatomic Power’s reactor could run on
thorium, but she believes it will be easier to obtain the uranium fuel.
The key, though, is not the underlying fuel, but the molten salt
reactor technology.
The molten salt reactor and thorium salt reactor each have same safety features and fuel burn-up. If you changed the moderator arrangement you could get each to run on the other fuel. They are cousins. We’ve been seeing benefits of molten salt reactors independent of whether they run on thorium or uranium. The molten salt is what makes it valuable. One key benefit is the ability to have a valve at the bottom, so if the system were to fail, it fails in a solid form rather than liquid or gaseous. The worst-case accident is confined to the site.
Another Approach: A Hybrid Market-Focused Initiative Using Solid Fuel And A Gas Generator
Transatomic Power is not the only group focused on a salt-cooled
nuclear technology. Another group involving the DOE, the Universities
of California and Wisconsin, and MIT is focused on a
fluoride-salt-cooled high temperature reactor (FHR) technology, combined
with a heat storage technology and gas turbines to create power that
can be dispatched as needed.
Charles Forsberg, director of the Integrated Research Project
Initiative, notes that the FHR approach – using low-enriched uranium –
may serve as a ‘halfway house’ to full development of a molten salt
reactor. A former Corporate Fellow at Oak Ridge and former Executive
Director of the Nuclear Fuel Cycle Study at MIT, with a long and
distinguished resume, Forsberg ran the salt-cooled projects at ORNL in
the 2000 timeframe.
He draws a distinction between salt-cooled reactors and molten salt
reactors where the fuel is actually dissolved in the salt itself.
Forsberg indicates that the Chinese are making significant investments
in both technologies, with plans to complete both a solid-fuel 10 MW
fluoride salt-cooled reactor and a liquid-fueled 2 MW molten salt
reactor within the next three years. According to Forsberg, the Chinese
have half a billion dollars invested in the program to date, with more
investment coming as they move towards commercialization in the
foreseeable future (the U.S. and China have a Memorandum of
Understanding to share information on the technologies).
Forsberg’s team believes that the solid fuel approach is the best way to approach the regulatory challenge.
Our perspective is that the solid fuel is a whole lot easier to develop and is the logical starting point. Get it to work and you have a smaller jump to the molten salt reactor where you have the fuel dissolved in the coolant. With permitting and regulatory, any time you go from solid fuel to liquid fuel you have to rethink the regulatory world.
Forsberg says that work with a clean salt cooled approach would
probably be viewed by the NRC as a variant of something they have seen
before, which is one reason to start with this approach. However, the
main challenge is economics, and here his team may have an advantage, as
they focus on using a hybrid reactor and turbine to create higher value
and dispatchable peak power.
What the team has done here is to re-think the nuclear process by
combining the reactor with a firebrick storage option. The latter
facilitates the relatively long-term storage of heat, which can then be
used when needed in the form of 600-700 degree centigrade air to power a
gas turbine for production of added electricity at times of high demand
and high prices.
Forsberg says the firebrick technology actually allows one to do this
faster than it can be done with a conventional gas turbine. It could
not have been done until recently: the previous gas turbines were not
good enough to integrate into the system. The firebrick technology is
over a century old and has seen long use in the steelmaking process,
while the FHR team plans to utilize modified GE turbines to produce
power. “Never invent a technology if you can borrow it,” he says.
Forsberg takes pains to point out that the gas turbine approach could
also be applied to molten salt technologies and thorium reactors to
improve the economics. And he’s convinced this technology could do a
better job than today’s batteries.
What happens if you bet on batteries? You could have several days of no wind or sun, so you need gas turbine backup. The actual cost of a battery is the cost of the battery plus back up generation capacity. In my case, I already own the gas turbine and I operate storage in the gas turbine.
As with the MSR, Forsberg is clear that the federal government will
have to play a role if this technology is ever to see the commercial
light of day.
The first case would have to be built by Uncle Sam…After a test reactor, getting vendors in would not be a big issues. All vendors say you need a test reactor before you get any serious money. The timeline is too long otherwise… We realize it’s going to require a heavy lift.
All in, Forsberg estimates this project will cost approximately two billion dollars.
The idea would be to get a test reactor, a 30-40 MW reactor…This (estimate) is based on looking at other projects with similar complexity…It’s a big integration project. The concrete and steel would probably cost $150-200 million. It’s the R&D necessary to get enough confidence that after you get done, you can say ‘I think we want a pre-commercial plant.’
That’s a big price tag, but not an enormous one in the scheme of
things. Given the opportunities at stake and the challenges faced by a
world that must move to cheaper and cleaner energy technologies, at
least some very smart people would argue that this is an investment
worth seriously considering.